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Revision Notes for Chemistry Chapter Alcohol, Phenol, and Ether XII


 

Some possible Revision Notes for the chapter "Alcohol, Phenol, and Ether" in Class 12 Chemistry are:

Introduction: 
• Alcohol, phenol, and ether are organic compounds that are characterized by the presence of the –OH functional group. 
• These compounds find wide applications in industries such as detergents, solvents, pharmaceuticals, and perfumes. 

Alcohol: 
• Alcohol is an organic compound that contains the –OH functional group bonded to a carbon atom. 
• They are classified as primary, secondary or tertiary based on the number of alkyl groups attached to the carbon bearing the –OH group. 
• They undergo substitution and elimination reactions. 
• The –OH group in alcohols is responsible for the properties such as polarity, hydrogen bonding and solubility in water. 

Phenol: 
• Phenol is an organic compound which consists of a hydroxyl group bonded to an aromatic ring. 
• Phenols are more acidic than alcohols due to the stability of the phenoxide ion. 
• They undergo substitution reactions with electrophiles such as nitric acid, bromine water, and halogens. 
• Phenols have a distinct odor and are used in the preparation of resins, plastics, and disinfectants. 

Ether: 
• Ether is an organic compound with the general formula R-O-R'. 
• They are classified as symmetrical or asymmetrical ethers based on the nature of the R and R' groups. 
• They are used as a solvent for lipophilic compounds and as an anesthetic. 
• They undergo nucleophilic substitution reactions when reacted with strong nucleophiles such as sodium hydride. 

Preparation of Alcohol: 
• Alcohol can be obtained by the fermentation of sugars such as glucose and sucrose. 
• Industrial methods include hydration of alkenes and reduction of carbonyl compounds. 

Preparation of Phenol: 
• Phenol is obtained by the destructive distillation of coal tar. 
• It can also be prepared by the hydrolysis of benzene diazonium chloride. 

Preparation of Ether: 
• Ether can be prepared by the Williamson ether synthesis which involves the reaction of an alkoxide ion with an alkyl halide. 

Properties of Alcohol, Phenol and Ether: 
• Alcohols, phenols, and ethers have a high boiling point due to the hydrogen bonding that occurs between the –OH and –O- groups. 
• They have a low melting point and are soluble in polar solvents due to their polar nature. 
• They undergo combustion reactions to produce CO2 and H2O. 

Conclusion: 
Alcohols, phenols, and ethers play an important role in various industrial and pharmaceutical applications. They possess unique properties that make them versatile and valuable compounds.


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